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KVPY2015ChemistryPractical Chemistry

A metal (X) dissolves both in dilute HCl and dilute NaOH to liberate H ₂ . Addition of NH ₄ Cl and excess NH ₄ OH to an HCl solution of X produce Y as a precipitate. Y is also produced by adding NH ₄ Cl to t he NaOH solution of X . The species X and Y , respectively, are

Options

  1. AZn and Zn ( OH )₂
  2. BAl and Al (OH) ₃
  3. CZn and Na ₂ ZnO ₂
  4. DAl and NaAlO ₂

Correct answer

B. Al and Al (OH) ₃

Step-by-step solution

array ll Zn + NaOH Na ₂ ZnO ₂ & Al + NaOH NaClO ₂ Zn + HCl ZnCl ₂+ H ₂ & Al + HCl AlCl ₃+ H ₂ array ZnCl ₂ gives no ppt with NH ₄ Cl + NH ₄ OH solution. But AlCl ₃ gives gelatinious white ppt of Al ( OH )₃ with NH ₄ Cl + NH ₄ OH .

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