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KVPY2014ChemistrySolid State

When 1.88 ~g of AgBr ( s ) is added to a 10⁻³ M aqueous solution of KBr , the concentration of Ag ⁺ is 5 10⁻¹⁰ M . if the same amount of AgBr ( s ) is added to a 10⁻² M aqueous solution of AgNO 3 , the concentration of Br is:

Options

  1. A9.4 10⁻⁹ M
  2. B5 10⁻¹⁰ M
  3. C1 10⁻¹¹ M
  4. D5 10⁻¹¹ M

Correct answer

D. 5 10⁻¹¹ M

Step-by-step solution

K _ SP AgBr = ( Ag ⁺ )( Br )= (5 10⁻¹⁰ ) (10⁻³ )=5 10⁻¹³ Concentration of Br in 10⁻² M aq AgNO ₃= Ksp AgBr [ Ag ⁺ ] = 5 10⁻¹³ (10⁻² ) =5 10⁻¹¹ ~m

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