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Manipal MET2016ChemistryGeneral Organic Chemistry

For the following, (i) I ⁻ (ii) Cl ⁻ (iii) Br ⁻ the increasing order of nucleophilicity would be

Options

  1. ABr ⁻ Cl ⁻ I ⁻
  2. BI ⁻ Cl ⁻ Br ⁻
  3. CCl ⁻ Br ⁻ I ⁻
  4. DI ⁻ Br ⁻ Cl ⁻

Correct answer

D. I ⁻ Br ⁻ Cl ⁻

Step-by-step solution

Halogens are the most reactive elements. High reactivity is due to their low dissociation energy. Further, among halogen, reactivity decreases as we move down the group. Hence, the correct order of nucleophilicity would be I ⁻ Br ⁻ Cl ⁻

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