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Manipal MET2012ChemistrySolid State

In a face-centred cubic arrangement of A and B atoms whose A atoms are at the corner of the unit cell and B atoms at the face-centre, one of A atom is missing from one corner in the unit cell. The simplest formula of the compound is

Options

  1. AA₂₄ B₇
  2. BA₇ B₄
  3. CA₇ B₂₄
  4. DA B₂

Correct answer

C. A₇ B₂₄

Step-by-step solution

No. of atoms of A from corners of unit cell = 7 8 No. of atoms of B from faces of unit cell =3 A: B= 7 8 : 3=7: 24 Thus, formula of the compound is A₇ B₂₄ .

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