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AIIMS 2006
Exam
AIIMS
Year
2006
Subject
Chemistry
Chapter
Chemical Kinetics

AIIMS 2006 · Chemistry · Chemical Kinetics

Assertion : According to transition state theory, for the formation...

Assertion : According to transition state theory, for the formation of an activated complex, one of the vibrational degrees of freedom is converted into a translational degree of freedom. Reason : Energy of the activated complex is higher than the energy of reactant molecules.

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of the assertion
  2. BIf both assertion and reason are true but reason is not the correct explanation of the assertion
  3. CIf assertion is true, but reason is false
  4. DBoth assertion and reason are false statements.

Correct answer

A. If both assertion and reason are true and reason is the correct explanation of the assertion

Step-by-step solution

:A+B⇌(AB)#→: A+B \rightleftharpoons(A B)^{\#} \rightarrow products. The activated complex can also be treated as a distinct chemical species in equilibrium with the reactants which then decompose into products. It is, however, a special molecule in which one vibrational degree of freedom has been converted to a translational degree of freedom along the reaction coordinate. It must be remembered that the activated complex is not merely an intermediate in process of breaking or forming of chemical bonds. It is unstable because it is situated at the maximum of the potential energy barrier separating the produts from the reactants. The difference between the energy of the activated complex (E1)\left(E_1\right) and the energy of the reactants (E2)\left(E_2\right) is the activation energy, EaE_a. E_1-E_2=E_a, E_1>>E_2 .
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