MHT CET20255 May 2025Evening ShiftChemistryAldehydes and KetonesActual
Identify the reaction so that carbonyl group of aldehydes and ketones is reduced to methylene group on treatment with Zinc-amalgam and concentrated hydrochloric acid.
Options
- AWolf-Kishner reduction.
- BStephan reaction.
- CClemmensen reduction.
- DEtard reaction.
Correct answer
C. Clemmensen reduction.
Step-by-step solution
The reaction characterized by reduction of a carbonyl group to a methylene group using zinc–amalgam and concentrated HCl is known as the Clemmensen reduction . In comparison, the Wolf–Kishner reduction employs hydrazine and a strong base such as KOH or NaOH ; , the Stephan reaction converts nitriles to aldehydes using stannous chloride and hydrochloric acid followed by hydrolysis, while the Étard reaction oxidizes a methyl group attached to an aromatic ring to an aldehyde using chromyl chloride. The correct answer