MHT CET202526 Apr 2025Morning ShiftChemistryAldehydes and KetonesActual
Identify the products of following reaction? Formaldehyde + Benzaldehyde [ ii) H ₃ O ⁺] i) conc. NaOH Products
Options
- APhenylmethanol and methanol
- BMethanol and benzoic acid
- CMethanoic acid and phenylmethanol
- DMethanoic acid and benzoic acid
Correct answer
C. Methanoic acid and phenylmethanol
Step-by-step solution
Crossed Cannizzaro Reaction of Formaldehyde and Benzaldehyde Formaldehyde ( HCHO ) and benzaldehyde ( C₆ H₅CHO ) are both aldehydes lacking alpha-hydrogens, qualifying them for the Cannizzaro reaction. In crossed Cannizzaro reactions, formaldehyde is preferentially oxidized due to its greater reactivity, while the partner aldehyde is reduced. Concentrated NaOH initiates hydride transfer: formaldehyde is oxidized to formate ion ( HCOO^- ), which upon acidification yields methanoic acid ( HCOOH ). Benzaldehyde is red