Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
MHT CET202526 Apr 2025Morning ShiftChemistryAldehydes and KetonesActual

Identify the products of following reaction? Formaldehyde + Benzaldehyde [ ii) H ₃ O ⁺] i) conc. NaOH Products

Options

  1. APhenylmethanol and methanol
  2. BMethanol and benzoic acid
  3. CMethanoic acid and phenylmethanol
  4. DMethanoic acid and benzoic acid

Correct answer

C. Methanoic acid and phenylmethanol

Step-by-step solution

Crossed Cannizzaro Reaction of Formaldehyde and Benzaldehyde Formaldehyde ( HCHO ) and benzaldehyde ( C₆ H₅CHO ) are both aldehydes lacking alpha-hydrogens, qualifying them for the Cannizzaro reaction. In crossed Cannizzaro reactions, formaldehyde is preferentially oxidized due to its greater reactivity, while the partner aldehyde is reduced. Concentrated NaOH initiates hydride transfer: formaldehyde is oxidized to formate ion ( HCOO^- ), which upon acidification yields methanoic acid ( HCOOH ). Benzaldehyde is red

Practice Aldehydes and Ketones on Quantrex Academy →

More from Aldehydes and Ketones

Which one of the following is the correct statement? 2026Match the reactions in List I with the final products formed as given in List II. List I List II W C ₆ H ₅ CH ₃ (i) CrO ₃ + ( CH ₃ CO )₂ O ; (ii) H ₂ O + heat P R ₂ CO X RCOOC ₂ H 2026Identify products [P₁ ] and [P₂ ] formed when Benzonitrile undergoes the following reactions. 2026Which of the following is NOT TRUE about nucleophilic addition reactions of aldehydes? 2026Propanal on reaction with dilute NaOH, undergoes aldol condensation resulting in the formation of a compound A. Identify the correct structure of A and name of the compound. 2026Etard reaction is a method of preparation of benzaldehyde by oxidation of toluene. The oxidizing agent used in this reaction is: 2026What are X and P in the following reaction sequence? 2026C ₃ H ₆ (i) BH ₃; (ii) H ₂ O ₂/ NaOH P CrO ₃, anhydrous medium Q (i) CH ₃ MgBr ; (ii) H ₂ O R + Mg(OH)Br The organic compounds P, Q and R are 2026 Full Aldehydes and Ketones list All MHT CET PYQs