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MHT CET202525 Apr 2025Evening ShiftChemistryAldehydes and KetonesActual

Which of the following is used as reagent in Etard reaction?

Options

  1. AChromium chloride
  2. BChromyl chloride
  3. CChromium oxide
  4. DChromic acid

Correct answer

B. Chromyl chloride

Step-by-step solution

In the Étard reaction, an aromatic or heterocyclic methyl group undergoes direct oxidation to an aldehyde using chromyl chloride ( CrO₂ Cl₂ ), proceeding through an intermediate chromyl ester that is hydrolyzed to yield the aldehyde product. For instance, toluene is converted to benzaldehyde: C₆ H₅-CH₃ CrO₂ Cl₂, CS₂ [C₆ H₅-CH(OCrOHCl₂)2] H₃ O^+ C₆ H₅-CHO Chromyl chloride ( CrO₂ Cl₂ ) is the specific reagent employed. Among the options, CrCl₃ is incorrect; CrO₃ and H2CrO4 are oxidizing agents but typically lead to o

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