MHT CET202519 Apr 2025Morning ShiftChemistryAldehydes and KetonesActual
Identify the product of following reaction. Formaldehyde + Benzaldehyde conc. NaOH H ₃ O ⁺ prodcut
Options
- APhenyl methanol and methanol
- BMethanol and benzoic acid
- CMethanoic acid and phenyl methanol
- DMethanoic acid and benzoic acid
Correct answer
C. Methanoic acid and phenyl methanol
Step-by-step solution
Crossed Cannizzaro reaction between formaldehyde and benzaldehyde: Both aldehydes lack -hydrogens, making them suitable for disproportionation under concentrated NaOH. Formaldehyde is preferentially oxidized due to its higher reactivity and lower steric hindrance. HCHO oxidizes to formic acid ( HCOOH ), which becomes sodium formate ( HCOONa ) in basic conditions and yields methanoic acid upon acidification. Benzaldehyde reduces to phenyl methanol ( C ₆ H ₅ CH ₂ OH ). The products are methanoic acid and phenyl metha