MHT CET2008ChemistryAldehydes and Ketones
Which reaction, intermediate is formed during the condensation reaction between acetaldehyde and formaldehyde ?
Options
- A: CH ₂ CHO
- BC ₂⁺ CHO
- C+ CH ₂ OH
- D: C HCHO
Correct answer
A. : CH ₂ CHO
Step-by-step solution
The -hydrogen atoms of acetaldehyde due to -E effect of > C = O group is slightly acidic in nature. In crossed aldol condensation between formaldehyde and acetaldehdye in the first step OH ⁻ ion (from the base added) abstracts one of these acidic -hydrogens to form carbanion or enolate ion which is stabilised by resonance.