MHT CET202520 Apr 2025Evening ShiftChemistryCarboxylic Acid DerivativesActual
Which among the following functional groups is reduced by diborane?
Options
- A-COOR
- B- COOH
- C- NO ₂
- D- X
Correct answer
B. - COOH
Step-by-step solution
Diborane ( B₂ H₆ ) reduces the following functional groups: Esters ( -COOR ) are reduced to primary alcohols: RCOOR' B₂ H₆ RCH₂ OH + R'OH . Carboxylic acids ( -COOH ) are reduced to primary alcohols: RCOOH B₂ H₆ RCH₂ OH . Diborane is particularly useful for selective reduction of carboxylic acids. Nitro groups ( -NO₂ ) are reduced to primary amines: RNO₂ B₂ H₆ RNH₂ . Alkyl halides ( -X ) are unreactive toward diborane under typical conditions. Therefore, options A, B, and C are reduced by diborane. A, B, C