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MHT CET202618 April 2026Evening ShiftChemistryGeneral Organic ChemistryActual

Which from following compounds is NOT optically active?

Options

  1. A3 - Bromohexane
  2. B2 - Bromo - 2 - methylbutane
  3. C2 - Bromopentane
  4. D2 - Bromo - 3 - methylbutane

Correct answer

B. 2 - Bromo - 2 - methylbutane

Step-by-step solution

The optical activity of a compound depends on the presence of a chiral carbon atom, which is bonded to four different groups. In 3-bromohexane, the C3 carbon is bonded to a hydrogen atom, a bromine atom, an ethyl group, and a propyl group. Since all four groups are different, it is chiral and optically active. In 2-bromo-2-methylbutane, the C2 carbon is bonded to a bromine atom, an ethyl group, and two identical methyl groups. Since two groups are the same, it does not have a chiral center and is optically inactive

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