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MHT CET202525 Apr 2025Evening ShiftChemistryGeneral Organic ChemistryActual

Which of the following compounds is an optically inactive compound?

Options

  1. A3-chlorohexane
  2. B2-chloro-2-methylbutane
  3. C2-chloropentane
  4. D2-chloro-3-methylbutane

Correct answer

B. 2-chloro-2-methylbutane

Step-by-step solution

Optical inactivity arises in achiral molecules. A compound lacking chiral centers or possessing a plane of symmetry is achiral and thus optically inactive. For 2-chloro-2-methylbutane, the carbon at position 2 is bonded to - Cl , - CH ₃ , - CH ₃ , and - CH ₂ CH ₃ , with two identical methyl groups making it non-chiral. No other chiral centers exist, and the molecule lacks a plane of symmetry, confirming achirality. In contrast, 3-chlorohexane has one chiral center at C3 with groups - H , - Cl , - CH ₂ CH ₃ , and -

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