AP EAMCET202421 May 2024Morning ShiftChemistryThermodynamics (C)Actual
Identify the correct statements from the following I. _ r G is zero for A B reaction II. The entropy of pure crystalline solids approaches zero as the temperature approaches absolute zero III. U of a reaction can be determined using bomb calorimeter
Options
- AI, II only
- BI, III only
- CII, III only
- DI, II, III
Correct answer
D. I, II, III
Step-by-step solution
(I) For equilibrium reaction Gibb's free energy i.e G _ r =0 (II) According to third law of thermodynamics, the entropy of pure crystalline solid approaches zero as the temperature approaches absolute zero. This is because there is perfect order in a crystal at absolute zero. (III)For a chemical reactions, heat absorbed at constant volume i.e U is measured in a bomb calorimeter.