MHT CET202611 April 2026Morning ShiftChemistrySurface ChemistryActual
Which of the following assertions about the extent of physisorption is correct?
Options
- AIncreases with increase in temperature
- BDecreases with increase in surface area
- CDecreases with increase in the strength of Van der Waals forces
- DDecreases with increase in temperature
Correct answer
D. Decreases with increase in temperature
Step-by-step solution
Physisorption is an exothermic process. According to Le Chatelier's principle, an increase in temperature shifts the equilibrium in the backward direction, leading to desorption. Thus, the extent of physisorption decreases with an increase in temperature. Additionally, the extent of physisorption increases with an increase in the surface area of the adsorbent and with an increase in the strength of Van der Waals forces between the adsorbate and adsorbent. Answer: Decreases with increase in temperature