MHT CET202613 April 2026Morning ShiftChemistryThermodynamics (C)Actual
Calculate the enthalpy change of the reaction, H ₂ (g) + Cl ₂ (g) 2 HCl(g) if bond energies (kJ mol ⁻¹ ): H–H = 436, Cl–Cl = 242, H–Cl = 431
Options
- A-184 kJ/mol
- B-246 kJ/mol
- C-242 kJ/mol
- D-431 kJ/mol
Correct answer
A. -184 kJ/mol
Step-by-step solution
The enthalpy change of the reaction is given by the difference between the sum of bond energies of reactants and the sum of bond energies of products. H = BE(Reactants) - BE(Products) For the given reaction: H ₂ (g) + Cl ₂ (g) 2 HCl(g) H = [ BE(H-H) + BE(Cl-Cl) ] - [2 BE(H-Cl) ] Substituting the given values: H = (436 + 242) - (2 431) H = 678 - 862 H = -184 kJ mol ⁻¹ Answer: -184 kJ/mol