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AIIMS 2003
Exam
AIIMS
Year
2003
Subject
Chemistry
Chapter
d and f Block Elements

AIIMS 2003 · Chemistry · d and f Block Elements

Assertion : Solution of Na_2 CrO_4 in water is coloured. Reason:...

Assertion : Solution of Na2CrO4\mathrm{Na}_2 \mathrm{CrO}_4 in water is coloured. Reason: Oxidation state of Cr\mathrm{Cr} in Na2CrO4\mathrm{Na}_2 \mathrm{CrO}_4 is +6 .

Options

  1. AIf both assertion and reason are true and the reason is the correct explanation of the assertion
  2. BIf both assertion and reason are true and the reason is not the correct explanation of the assertion
  3. CIf assertion is true but reason is false
  4. DIf both assertion and reason are false.

Correct answer

B. If both assertion and reason are true and the reason is not the correct explanation of the assertion

Step-by-step solution

Na2CrO4\mathrm{Na}_2 \mathrm{CrO}_4 solution in water is yellow in colour, when acidified changes to orange colour (due to the formation of Cr2O72−\mathrm{Cr}_2 \mathrm{O}_7^{2-} ions). \mathrm{Na}}_{2} \mathrm{CrO}}_{4}+\mathrm{H}}_{2} \mathrm{SO}}_{4} \rightarrow \mathrm{Na}}_{2} \mathrm{Cr}}_{2} \mathrm{O}}_{7}+ \mathrm{Na}}_{2} \mathrm{SO}}_{4}+ \mathrm{H}}_{2} O\mathrm{O}Oxidation state : Na2CrO4\mathrm{Na}_2 \mathrm{CrO}_4 Let oxidation state of Cr\mathrm{Cr} be xx. \Rightarrow 2(+1)+x+4(-2)=0 \Rightarrow x=+6 . \text{. }
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