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JEE MainChemistrys Block Elements

Given below are four statements regarding s-block elements: (A) The hydration enthalpy of Mg ²⁺ is more negative than that of Na ^+ . (B) The aqueous ionic mobility of alkali metals follows the order Cs ^+ > Rb ^+ > K ^+ > Na ^+ > Li ^+ . (C) The hydrated radius of Be ²⁺ is smaller than that of Ba ²⁺ . (D) The magnitude of hydration enthalpy decreases down the group for alkaline earth metals. Choose the most appropri

Options

  1. A(A), (B), (C) and (D)
  2. B(A) and (D) only
  3. C(A), (B) and (D) only
  4. D(B), (C) and (D) only

Correct answer

C. (A), (B) and (D) only

Step-by-step solution

Statement (A) is correct: Alkaline earth metal ions like Mg ²⁺ have a higher charge and smaller size than alkali metal ions like Na ^+ , leading to a higher charge density and a more negative hydration enthalpy. Statement (B) is correct: Smaller bare ions are more extensively hydrated. Thus, Li ^+ has the largest hydrated radius and consequently the lowest ionic mobility in aqueous solution, while Cs ^+ has the highest ionic mobility. Statement (C) is incorrect: Due to its very small bare ionic size, Be ²⁺ is heavi

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