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MHT CET 202626 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
26 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Biomolecules

MHT CET 2026 · 26 April · Morning Shift · Chemistry · Biomolecules

Identify the product formed when glucose is treated with dil. HNO_3...

Identify the product formed when glucose is treated with dil. HNO3\text{HNO}_3.

Options

  1. ASaccharic acid
  2. BOxalic acid
  3. CGluconic acid
  4. DMalonic acid

Correct answer

A. Saccharic acid

Step-by-step solution

Glucose on oxidation with dilute nitric acid (HNO3\text{HNO}_3) yields a dicarboxylic acid known as saccharic acid.

Dilute HNO3\text{HNO}_3 is a strong oxidizing agent that oxidizes both the terminal aldehyde group (−CHO-\text{CHO}) and the terminal primary alcohol group (−CH2OH-\text{CH}_2\text{OH}) of glucose into carboxylic acid groups (−COOH-\text{COOH}).

CHO−(CHOH)4−CH2OH→dil. HNO3COOH−(CHOH)4−COOH\text{CHO}-(\text{CHOH})_4-\text{CH}_2\text{OH} \xrightarrow{\text{dil. HNO}_3} \text{COOH}-(\text{CHOH})_4-\text{COOH}

Thus, the product formed is saccharic acid.

Answer: Saccharic acid
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