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MHT CET 202625 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
25 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

MHT CET 2026 · 25 April · Evening Shift · Chemistry · Carboxylic Acid Derivatives

The order of strength of carboxylic acid is Find the correct order.

The order of strength of carboxylic acid is
The order of strength of carboxylic acid is Find the correct order.
Find the correct order.

Options

  1. AIII>I>II\text{III} > \text{I} > \text{II}
  2. BI>II>III\text{I} > \text{II} > \text{III}
  3. CII>III>I\text{II} > \text{III} > \text{I}
  4. DIII>II>I\text{III} > \text{II} > \text{I}

Correct answer

A. III>I>II\text{III} > \text{I} > \text{II}

Step-by-step solution

The acidic strength of a carboxylic acid depends on the stability of its conjugate base (carboxylate anion). Electron-withdrawing groups (−I-I effect) stabilize the anion and increase acidic strength.

In the given compounds, the oxygen atom in the ring is more electronegative than carbon and exerts a −I-I effect.

In structure (I), the oxygen atom is at the 4-position relative to the carbon bearing the −COOH-\text{COOH} group.

In structure (II), there is no electronegative heteroatom in the ring, making it the least acidic among the three.

In structure (III), the oxygen atom is at the 3-position relative to the −COOH-\text{COOH} group.

The −I-I effect is distance-dependent; its strength decreases as the distance between the electron-withdrawing group and the acidic group increases. Since the oxygen atom in (III) is closer to the −COOH-\text{COOH} group than in (I), the −I-I effect is stronger in (III) compared to (I).

Therefore, the carboxylate anion of (III) is more stable than that of (I), making (III) a stronger acid than (I). Both (I) and (III) are stronger acids than (II) due to the presence of the electron-withdrawing oxygen atom.

The correct order of acidic strength is III>I>II\text{III} > \text{I} > \text{II}.

Answer: III>I>II\text{III} > \text{I} > \text{II}
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