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Carboxylic Acid Derivatives — NEET UG Chemistry PYQs

368 previous year questions from Carboxylic Acid Derivatives with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

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1

Which of the following acids is tricarboxylic acid?

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2

Identify the process of making soap by the hydrolysis of fats and oils.

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3

Identify the trend of solubility of carboxylic acid in water.

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4

Identify the product of acid hydrolysis of propane nitrile.

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5

Which of the following acid does NOT contain -COOH group?

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6

Which of the following acid has the highest acid strength? (A) Acetic acid (B) fluoroacetic acid (C) 4-Nitrobenzoic acid (D) 4-Methyl Benzoic acid is

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7

What is the number of - COOH groups in a citric acid molecule?

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8

The order of strength of carboxylic acid is Find the correct order.

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9

Identify the organic compound having highest boiling point from following.

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10

Given below are two statements: Statement-I : Oxidation of p -nitrotoluene with acidic KMn O₄ gives an acid that is stronger than benzoic acid. Statement-II : Reduction of p -nitro

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11

The correct order of decreasing acidity of the following aliphatic acids is :-

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12

For the given reaction: 'P' is

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13

Match List I with List II. Choose the correct answer from the options given below:

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14

Weight (g) of two moles of the organic compound, which is obtained by heating sodium ethanoate with sodium hydroxide in presence of calcium oxide is :

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15

The following conversion is known as

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16

The product formed from the following reaction sequence is:

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17

RMgX + CO 2 → ether dry Y ⟶ H 3 O + RCOOH What is Y in the above reaction?

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18

The incorrect method to synthesize benzaldehyde is:

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19

Consider the above reaction and identify the missing reagent/chemical.

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20

Which of the following acid will form an (a) Anhydride on heating and (b) Acid imide on strong heating with ammonia?

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21

The major product of the following reaction is:

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22

Assertion : Anhydrides are more reactive than esters for nucleophilic substitution reaction. Reason : RCOO ⁻ is better leaving group than R - O ⁻ .

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23

Assertion : CH ₃ COOH but not HCOOH can be halogenated in presence of red P and Cl ₂ . Reason : Both formic acid and CH ₃ COOH are highly soluble in water.

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24

Neopentyl chloride reacts with benzene in presence of a Lewis acid ( AlCl ₃ ) to form

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25

What are the suitable reagents for the following conversion?

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26

Neopentyl chloride reacts with benzene in presence of a Lewis acid ( AlCl ₃ ) to form

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27

Consider the following set of reactions : The structure of D would be

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28

Consider the following compounds. The decreasing order of decarboxylation is

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29

Consider the following compounds. The decreasing order of decarboxylation is

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30

When a mixture of 1-hexanol and hexanoic acid in diethyl ether is shaken with an aqueous NaHCO ₃ solution, then which of the following is right distribution?

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31

Which one of the following esters gets hydrolyzed most easily under alkaline conditions?

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32

Benzoic acid is treated with lithium aluminium hydride. The compound obtained is

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33

Assertion: Formic acid reduces mercuric chloride to mercurous chloride on heating, while acetic acid does not. Reason : Formic acid is a stronger acid than acetic acid.

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34

When a mixture of 1-hexanol and hexanoic acid in diethyl ether is shaken with an aqueous NaHCO ₃ solution, then which of the following is right distribution?

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35

The relative reactivities of acyl compounds towards nucleophilic substitution are in the order of

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36

Which one of the following reactions does not form gaseous product?

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37

Assertion: ( CH ₃ )₃ CCOOH does not give HVZ reaction. Reason: ( CH ₃ )₃ CCOOH does not have -hydrogen atom.

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38

The relative reactivities of acyl compounds towards nucleophilic substitution are in the order of

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39

Which one of the following reactions does not form gaseous product?

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40

The correct order of increasing acidic strength is

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41

The correct order of increasing acidic strength is

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42

Acetic anhydride is prepared in the laboratory by heating sodium acetate with

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43

In a set of reactions, acetic acid yielded a product S . CH ₃ COOH SOCl ₂ P Benzene Anhy. AlCl ₃ Q HCN R HOH S The structure of S would be

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44

Acetic anhydride is prepared in the laboratory by heating sodium acetate with

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45

In a set of reactions, m -bromobenzoic acid gave a product D . Identify the product D .

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46

Maximum decarboxylation occurs in

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47

In a set of reactions, ethyl benzene yielded a product D . ' D ' would be

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48

Consider the following reaction, Phenol Zn dust X Anhydrous AlCl ₃ CH ₃ Cl Y array l Alkaline KMnO array Z , the product, Z , is

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49

Propionic acid with Br ₂- P yields a dibromo product. Its structure would be

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50

Consider the following reaction :

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51

Predict the product :

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52

Trichloroacetaldehyde, CCl ₃ CHO reacts with chlorobenzene in presence of sulphuric acid and produces -

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53

Assertion : Esters which contain -hydrogens undergo Claisen condensation. Reason : LiAlH ₄ reduction of esters gives acids.

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54

Sodium formate on heating gives

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55

Sodium formate on heating gives

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56

In a set of reactions, acetic acid yielded a product D . CH ₃ COOH SOCl ₂ A [ anhyd. AlCl ₃] Benzene B HCN C HOH D The structure of D would be

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57

Which of the following undergoes nucleophilic substitution exclusively by S _ N 1 mechanism?

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58

Phenol and benzoic acid are distinguished by

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59

In a set of reaction acetic acid yielded a product 'd'.

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60

Which of the following has the maximum acidic strength ?

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61

CH ₃ COOH PBr ₂ CH ₂ BrCOOH This reaction is called

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62

The OH group of an alcohol or the COOH group of a carboxylic acid can be replaced by - Cl using:

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63

o -Toluic acid on reaction with Br ₂+ Fe gives

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64

Phospholipids are esters of glycerol with

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65

In the above reaction product ' P ' is:

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66

In the following reaction order, B is

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67

Strongest acid among the following is

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68

What type of compound is formed when Grignard reagents react with carbon dioxide and mineral acid is added?

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69

What is the usual product of the oxidation of toluene and its derivatives using strong oxidising agents?

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70

What is the expected effect of resonance on the acidity of carboxylic acids?

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71

What is the main reason for the lower electrophilicity of the carboxylic carbon in carboxylic acids?

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72

Why is thionyl chloride (SOCl 2 ) preferred for the reaction involving carboxylic acids and chlorine atom replacement?

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73

What chemical reactions can replace the hydroxyl group of carboxylic acids with a chlorine atom?

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74

What is the name of the reaction in which alkali metal salts of carboxylic acids undergo electrolysis to form hydrocarbons?

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75

What is the result of hydrolyzing anhydrides with water?

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76

What structural feature in carboxylic acids contributes to their resonance stabilization of the carboxylic carbon?

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77

Which reagents are NOT typically used to oxidize alkylbenzenes to aromatic carboxylic acids?

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78

What functional group characterizes carboxylic acids?

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79

What is the primary use of ethanoic acid in the food industry?

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80

What is the product formed when toluene or substituted toluene is treated with chromic oxide in acetic anhydride?

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81

What is the immediate product formed when Grignard reagents react with carbon dioxide?

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82

What type of reaction is the decarboxylation of carboxylic acids?

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83

What is the role of mineral acid in the preparation of carboxylic acids from Grignard reagents and carbon dioxide?

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84

How is the strength of an acid generally indicated for convenience?

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85

What are esters and anhydrides considered in relation to carboxylic acids?

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86

What is the common feature of PCl 5 , PCl 3, or SOCl 2 in their reactions with carboxylic acids?

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87

What functional group characterises carboxylic acids?

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88

What is the primary role of the carboxyl group in electrophilic substitution reactions of aromatic carboxylic acids?

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89

What is the role of red phosphorus in the Hell-Volhard-Zelinsky reaction?

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90

How many times greater is the number of carbon atoms in the hydrocarbons formed in Kolbe electrolysis compared to the alkyl group of the carboxylic acid?

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91

What is required for the decarboxylation of carboxylic acids when their sodium salts are heated with soda lime?

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92

What is the role of ammonia in the reaction with carboxylic acids?

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93

Which products are obtained from the reduction of carboxylic acids using lithium aluminium hydride?

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94

What is the composition of the hydrocarbons formed in Kolbe electrolysis in relation to the alkyl group of the carboxylic acid?

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95

What are nitriles hydrolyzed into during the preparation of carboxylic acids?

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96

What are carboxylic acids esterified with in the presence of a mineral acid catalyst?

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97

Which functional group characterises esters?

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98

Which type of alkyl groups are oxidized to carboxylic acids when using chromic acid or potassium permanganate?

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99

Which reaction converts acid chlorides into carboxylic acids more readily?

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100

How does the electrophilicity of the carboxylic carbon compare to the carbonyl carbon in carboxylic acids?

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101

Why does sodium borohydride not reduce the carboxyl group in carboxylic acids?

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102

What type of substitution reactions do aromatic carboxylic acids undergo?

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103

What is the application of esters of benzoic acid in the field of perfumery?

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104

In which industries is methanoic acid commonly used?

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105

Which functional group is part of the carboxyl group?

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106

How do electron donating groups affect the acidity of carboxylic acids?

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107

What is the role of alkali metal salts in Kolbe electrolysis?

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108

In carboxylic acids, how are the bonds to the carboxyl carbon oriented in terms of their plane arrangement?

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109

Why do aromatic carboxylic acids not undergo Friedel-Crafts reactions?

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110

What is the name of the reaction in which carboxylic acids with an α-hydrogen are halogenated to form α-halocarboxylic acids?

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111

What happens to tertiary alkyl groups during the oxidation of alkylbenzenes to carboxylic acids?

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112

Why are carboxylic acids more acidic than phenols?

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113

What is the function of sodium benzoate in the food industry?

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114

In comparison to alcohols and many simple phenols, where do carboxylic acids rank in terms of acidity?

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115

What does the term "decarboxylation" refer to in the context of carboxylic acids?

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116

Which carboxylic acid is nearly insoluble in cold water?

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117

What is the initial product formed when carboxylic acids react with ammonia?

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118

What natural compounds are esters of glycerol and higher members of aliphatic carboxylic acids?

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119

Why does the solubility of higher carboxylic acids decrease as the number of carbon atoms in the molecule increases?

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120

In which industry is ethanoic acid used as a solvent?

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