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MHT CET 202625 AprilEvening Shift
Exam
MHT CET
Year
2026
Date
25 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Ionic Equilibrium

MHT CET 2026 · 25 April · Evening Shift · Chemistry · Ionic Equilibrium

The degree of dissociation of weak acid is directly proportional to

The degree of dissociation of weak acid is directly proportional to

Options

  1. Avolume of the solution containing 11 mole of the weak acid
  2. Bsquare of volume of the solution containing 11 mole of the weak acid
  3. Csquare root of the volume containing 11 mole of the weak acid
  4. Dconcentration of solution containing 11 mole of the weak acid

Correct answer

C. square root of the volume containing 11 mole of the weak acid

Step-by-step solution

According to Ostwald's dilution law for a weak acid HAHA, the dissociation constant KaK_a is given by:

Ka=Cα21−αK_a = \dfrac{C\alpha^2}{1-\alpha}

For a weak acid, the degree of dissociation α\alpha is very small (α≪1\alpha \ll 1), so 1−α≈11-\alpha \approx 1.

Ka≈Cα2⇒α=KaCK_a \approx C\alpha^2 \Rightarrow \alpha = \sqrt{\dfrac{K_a}{C}}

The concentration CC is the number of moles per unit volume. For 11 mole of the weak acid, C=1VC = \dfrac{1}{V}, where VV is the volume of the solution.

Substituting C=1VC = \dfrac{1}{V} into the expression for α\alpha:

α=Ka×V\alpha = \sqrt{K_a \times V}

α∝V\alpha \propto \sqrt{V}

Thus, the degree of dissociation is directly proportional to the square root of the volume of the solution containing 11 mole of the weak acid.

Answer: square root of the volume containing 11 mole of the weak acid
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