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NEET Ionic Equilibrium PYQs with Solutions

764 previous year questions from Ionic Equilibrium (NEET UG Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

764 questionsChemistry2001–2026Answers + solutions

About Ionic Equilibrium PYQs

Ionic Equilibrium has 764 previous year questions in the Quantrex Academy NEET UG Chemistry bank. The 220 questions in this list come from NEET (116), AIIMS (47), MHT CET Medical (34) and 1 other source, spanning 2001 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 38
  • 2025: 1
  • 2024: 2
  • 2023: 3
  • 2022: 2
  • 2021: 1
  • 2020: 4
  • 2019: 7
  • 2018: 4
  • 2017: 5
  • 2016: 7
  • 2015: 4

Ionic Equilibrium questions with solutions

1

What amount of NaOH should be dissolved in a 500 mL solution, so that the p^H of solution is 12 at 298 K ?

MHT CET Medical 2026 Solution
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2

Which of the following buffer solutions is used for precipitation of cations of the III A group?

MHT CET Medical 2026 Solution
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3

The degree of dissociation of weak acid is directly proportional to

MHT CET Medical 2026 Solution
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4

Which from the following is Lewis base?

MHT CET Medical 2026 Solution
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5

The solubility of Fe(OH)_3 is x mole per liter. Find its K_ sp .

MHT CET Medical 2026 Solution
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6

The Basic buffer solution is made with 0.1\ M\ NH_4OH and 0.2\ M\ NH_4Cl . If K_b for the base is 1.8 × 10^ -5 , what is the pH of the buffer?

MHT CET Medical 2026 Solution
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7

The hydrogen ion concentration of the ocean is about 2 × 10^ -9 \ M . What is the pOH of ocean?

MHT CET Medical 2026 Solution
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8

Calculate the dissociation constant of a weak monobasic acid if it is 0.04% dissociated in a 0.01M solution.

MHT CET Medical 2026 Solution
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9

Calculate the solubility of AgCl in mol/dm^3 at 25\ ^ ^ ∘ C . Given: K_ sp \ (AgCl) = 1.8 × 10^ -10

MHT CET Medical 2026 Solution
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10

A weak monobasic acid is 0.05\ \% dissociated in its solution, find the degree of dissociation.

MHT CET Medical 2026 Solution
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11

Solubility of MA_2 type of electrolyte is 0.5 × 10^ -4 \ mol/litre . Then find out k_ sp of electrolyte?

MHT CET Medical 2026 Solution
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12

Which of the following aqueous solutions of salts is neutral?

MHT CET Medical 2026 Solution
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13

Calculate the amount of NaOH in g/L in a one L solution of it with the pH of 12. (Molar mass of NaOH=40 g/mol)

MHT CET Medical 2026 Solution
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14

The solubility of AgBr at 298 K is 2×10^ -7 \ kg/dm^3 . Find the solubility product of AgBr at same temperature. [Molar mass of AgBr=188 g/mol]

MHT CET Medical 2026 Solution
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15

Which of the following salts of weak acids and weak bases on hydrolysis turns red litmus blue? [K_a for acetic acid = 1.8×10^ -5 , K_a for hydrofluoric acid = 6.8×10^ -4 , K_a for

MHT CET Medical 2026 Solution
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16

What is pH of HCl solution containing 0.365 g of HCl in 100 mL of solution, assuming complete dissociation at 298 K? ( Molar mass of HCl = 36.5 g/mol)

MHT CET Medical 2026 Solution
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17

Which from the following is NOT a buffer solution?

MHT CET Medical 2026 Solution
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18

Calculate the pH of the buffer solution consists of 0.005 M weak acid and 0.02 M of its salt with strong base BA. [ pK_a = 3.4437 ]

MHT CET Medical 2026 Solution
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19

The solubility product of Ag_2CrO_4 is 4 × 10^ -12 . What is the amount of Ag_2CrO_4 in gram present in 100 ml its saturated solution? (molar mass of Ag_2CrO_4 = 331.73 g/mol).

MHT CET Medical 2026 Solution
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20

The pH of HCl and H_2SO_4 is same at same temperature. What is the ratio of molar concentration of HCl to H_2SO_4 ?

MHT CET Medical 2026 Solution
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21

Identify the strong electrolyte.

MHT CET Medical 2026 Solution
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22

Calculate the solubility product of Ca(OH)_2 if solubility of it is 3 mol dm^ -3 at 25^ ^ ∘ C .

MHT CET Medical 2026 Solution
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23

Which of the following aqueous salt solutions is acidic?

MHT CET Medical 2026 Solution
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24

What is the pH of buffer solution containing 10 times higher molar concentration of weak base than the molar concentration of salt of weak base with strong acid at 298 K? (K_b of

MHT CET Medical 2026 Solution
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25

Find the pH of 0.02\ M\ HCl .

MHT CET Medical 2026 Solution
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26

The solubility product of aluminium hydroxide at 298 K is 4.2 × 10^ -14 . Calculate its solubility in mol/L at same temperature.

MHT CET Medical 2026 Solution
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27

Find the p K_b of the weak base BOH, if its K_b is 1 × 10^ -5 ?

MHT CET Medical 2026 Solution
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28

Dissociation constant values for H_2CO_3 , CH_3COOH , HCN, and HF are 4.3 × 10^ -7 , 1.8 × 10^ -5 , 4.0 × 10^ -10 and 7.2 × 10^ -4 respectively, at 25^ ^ ∘ C . Identify the

MHT CET Medical 2026 Solution
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29

If K_a of weak acid HA is 1 × 10^ -7 , calculate the [H_3O^+] of 0.1\ M solution at equilibrium.

MHT CET Medical 2026 Solution
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30

Calculate the pH of the resulting solution obtained by mixing 60\ mL0.1\ M HCl and 40\ mL0.1\ M NaOH.

MHT CET Medical 2026 Solution
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31

In the washing of precipitates, the wash liquid should contain a common ion with the precipitate for

MHT CET Medical 2026 Solution
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32

The degree of dissociation of a monobasic acid in its 0.1M solution at 300 K is 1.342 × 10^ -2 . Calculate the degree of dissociation of the same acid in its 0.02M solution.

MHT CET Medical 2026 Solution
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33

Calculate the percent dissociation of a weak mono-acidic base if its concentration is 0.02 M. [ K_b for weak mono-acidic base = 1.8 × 10^ -5 ]

MHT CET Medical 2026 Solution
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34

Identify from following an example of Lewis acid.

MHT CET Medical 2026 Solution
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35

In a qualitative analysis Bi^ 3+ is detected by appearance of precipitate of BiO(OH)(s) . Calculate pH when the following equilibrium exists at 298 K : BiO(OH)(s) leftharpoons

NEET 2026 Solution
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36

At 298 K, a certain buffer solution contains equal concentrations of X^ - and HX , K_b for X^ - is 10^ -10 . What is the pH of this buffer solution ?

NEET 2026 Solution
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37

The correct order of solubility of the given salts in water at 298 K is Salt K_ sp at 298 K AgBr 5.0×10^ -13 Zn(OH) _2 1.0×10^ -15 Hg _2 Cl _2 1.3×10^ -18

NEET 2026 Solution
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38

Phenolphthalein is used as an indicator for the titration of sodium hydroxide solution against a standard solution of oxalic acid. The colour change that is observed at an

NEET 2026 Solution
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39

Phosphoric acid ionizes in three steps with their ionization constant values K_ a_1 , ~K_ a_2 and K_ a_3 , respectively, While K is the overall ionization constant. Which of the

NEET 2025 Solution
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40

The ratio of solubility of AgCl in 0.1 M KCl solution to the solubility of AgCl in water is: (Given : Solubility product of AgCl=10^ -10 )

NEET 2024 Solution
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41

Which indicator is used in the titration of sodium hydroxide against oxalic acid and what is the colour change at the end point?

NEET 2024 Solution
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42

An acidic buffer is prepared by mixing:

NEET 2023 Solution
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43

For a weak acid HA , the percentage of dissociation is nearly 1 \% at equilibrium. If the concentration of acid is 0.1 ~mol ~L^ -1 , then the correct option for its K_ a at the

NEET 2023 Solution
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44

Amongst the given options which of the following molecules/ion acts as a Lewis acid?

NEET 2023 Solution
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45

The pH of the solution containing 50mL each of 0 . 10M sodium acetate and 0 . 01M acetic acid is [Given pK _ a of CH _ 3 COOH = 4 . 57 ]

NEET 2022 Solution
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46

0.01 M acetic acid solution is 1 \% ionised, then pH of this acetic acid solution is :

NEET 2022 Solution
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47

The pK _ b of dimethylamine and pK _ a of acetic acid are 3 . 27 and 4 . 77 respectively at T ( K ) . The correct option for the pH of dimethylammonium acetate solution is:

NEET 2021 Solution
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48

The solubility product for a salt of the type AB is 4 × 10 ^ - 8 . What is the molarity of its saturated solution?

NEET 2020 Solution
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49

HCl was passed through a solution of CaCl _ 2 , MgCl _ 2 and NaCl . Which of the following compound(s) crystallise(s)?

NEET 2020 Solution
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50

Find out the solubility of Ni (OH) _ 2 in 0.1MNaOH . Given that the ionic product of Ni (OH) _ 2 is 2 × 10 ^ – 15 .

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51

Which among the following salt solutions is basic in nature?

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52

Assertion : Some salts are sparingly soluble in water at room temperature. Reason : The entropy increases on dissolving the salts.

AIIMS 2019 Solution
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53

Which of the following has maximum solubility at low pH ?

AIIMS 2019 Solution
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54

If 50 ml of 0.1 HBr is mixed with 50 ml 0.2 M NaOH , find pH of resulting mixture

JIPMER 2019 Solution
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55

The pH of 0.01 M NaOH(a q) solution will be

NEET 2019 Solution
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56

Which of the following cannot act both as Bronsted acid and as Bronsted base?

NEET 2019 Solution
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57

The molar solubility of CaF_2 (K_ sp =5.3 × 10^ -11 ) in 0.1 M solution of NaF will be

NEET 2019 Solution
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58

pH of a saturated solution of Ca (OH) _ 2 is 9 . The solubility product ( K _ sp ) of Ca (OH) _ 2 is:

NEET 2019 Solution
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59

Calculate ionisation constant for pyridinium hydrogen chloride. (Given that H^ + ion concentration is 3.6 × 10^ -4 M and its concentration is 0.02 M .)

AIIMS 2018 Solution
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60

When 50 ~mL of 0.1 M NH_3 is mixed with 10 ~mL of 0.1 M HCl then what is the pH of resultant solution? (p K_b=4.75)

AIIMS 2018 Solution
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61

Following solutions were prepared by mixing different volumes of NaOH and HCl of different concentrations. (i) 60mL(M)/(10)HCl + 40mL(M)/(10)NaOH (ii) 55mL(M)/(10)HCl +

NEET 2018 Solution
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62

The solubility of BaSO _ 4 in water is 2 .42 × 10 ^ - 3 gL ^ - 1 at 298K . The value of its solubility product ( K _ sp ) will be (Given- the molar mass of BaSO _ 4 = 233g mol ^

NEET 2018 Solution
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63

Calculate the overall complex dissociation equilibrium constant for the [Cu(NH_3)_4]^ 2+ ions, given that stability constant (β_4) for this complex is 2.1 × 10^ 13 .

AIIMS 2017 Solution
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64

ZnO is white when cold and yellow when heated. It is due to the development of

AIIMS 2017 Solution
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65

K_a for HCN is 5 × 10^ -10 at 25^ ∘ C . For maintaining a constant pH=9 , the volume of 5 M KCN solution required to be added to 10 ~mL of 2 M HCN solution is

AIIMS 2017 Solution
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66

When 750 mL of 0.5 M HCl is mixed with 250 mL of 2 M NaOH solution, the value of pH will be

JIPMER 2017 Solution
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67

Concentration of the Ag ^ + ions in a saturated solution of Ag _ 2 C _ 2 O _ 4 is 2 .2 × 10 ^ - 4 mol L ^ - 1 . Solubility product of Ag _ 2 C _ 2 O _ 4 is

NEET 2017 Solution
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68

Assertion : H_2 ~S is stronger acid than PH_3 . Reason : S is more electronegative than P , conjugate base HS^ - is more stable than H_2 P^ - .

AIIMS 2016 Solution
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69

K_p for the reaction A leftharpoons B is 4 . If initially only A is present then what will be the partial pressure of B after equilibrium?

AIIMS 2016 Solution
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70

100 mL of a solution contains 2 g of acetic acid and 3 g of sodium acetate providing K_a=1.8 × 10^ -5 , then choose the correct option.

JIPMER 2016 Solution
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71

Aqueous solution of AlCl_3 is acidic towards litmus while of NaCl is not. The correct reason behind this is

JIPMER 2016 Solution
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72

The percentage of pyridine ( C _ 5 H _ 5 N) that forms pyridinium ion ( C _ 5 H _ 5 N ^ + H) in a 0 . 10M aqueous pyridine solution ( K _ b for C _ 5 H _ 5 N = 1 .7 × 10 ^ - 9 ) is

NEET 2016 Solution
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73

The solubility of AgCl(s) with solubility product 1.6 × 10 ^ - 10 in 0.1MNaCl solution would be

NEET 2016 Solution
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74

MY and N Y _ 3 , two nearly insoluble salts, have the same K _ sp values of 6.2 × 10 ^ - 13 at room temperature. Which statement would be true in regard to MY and N Y _ 3 ?

NEET 2016 Solution
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75

The pair of amphoteric hydroxides is

AIIMS 2015 Solution
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76

Assertion: Sb_2 ~S_3 is not soluble in yellow ammonium sulphide. Reason : The common ion effect due to S^ 2- ions reduces the solubility of Sb_2 ~S_3 .

AIIMS 2015 Solution
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77

Which one of the following pairs of solution is not an acidic buffer?

NEET 2015 Solution
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78

What is the pH of the resulting solution when equal volumes of 0.1 M NaOH and 0.01 M HCl are mixed?

NEET 2015 Solution
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79

Assertion: Mixture of CH_3 COOH and CH_3 COONH_4 is an example of acidic buffer. Reason: Acidic buffer contains equimolar mixture of weak acid and its salt with weak base.

AIIMS 2014 Solution
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80

A buffer solution is prepared in which the concentration of NH_3 is 0.30 M and the concentration of NH_4^ + is 0.20 M . If the equilibrium constant, K_b for NH_3 equals 1.8 × 10^

JIPMER 2014 Solution
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81

Which of the following salts will give highest pH in water?

NEET 2014 Solution
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82

What will be the solubility product of A X_3 ?

AIIMS 2013 Solution
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83

p K_a of acetic acid and p K_b of ammonium hydroxide are 4.76 and 4.75 respectively. Calculate the pH of ammonium acetate solution.

JIPMER 2013 Solution
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84

Accumulation of lactic acid (HC_3 H_5 O_3) , a monobasic acid in tissues leads to pain and a feeling of fatigue. In a 0.10 M aqueous solution, lactic acid is 3.7 \% dissociates.

NEET 2013 Solution
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85

At 100^ ∘ C the K_w of water is 55 times its value at 25^ ∘ C . What will be the pH of neutral solution? ( 55=1.74)

NEET 2013 Solution
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86

The dissociation constant of a weak acid is 1 × 10^ -4 . In order to prepare a buffer solution with a pH =5 , the [Salt]/ [Acid] ratio should be:

NEET 2013 Solution
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87

Which of these is least likely to act as a Lewis base?

NEET 2013 Solution
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88

Which has the highest pH ?

AIIMS 2012 Solution
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89

The pH value of 0.001 M aqueous solution of NaCl is

JIPMER 2012 Solution
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90

The solubility product of Hg_2 I_2 is equal to

JIPMER 2012 Solution
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91

Which buffer solution comprising of the following has its pH value greater than 7 ?

JIPMER 2012 Solution
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92

pH of a saturated solution of Ba(OH)_2 is 12. The value of solubility product K_ sp of Ba(OH)_2 is

NEET 2012 Solution
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93

Equimolar solutions of the following substances were prepared separately. Which one of these will record the highest pH value?

NEET 2012 Solution
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94

Buffer solutions have constant acidity and alkalinity because

NEET 2012 Solution
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95

The compound which does not exist as hydrate form

AIIMS 2011 Solution
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96

K_ s p of CaSO_4 · 5 H_2 O is 9 × 10^ -6 , find the volume for 1 ~g of CaSO_4 (M.wt. = 136).

AIIMS 2011 Solution
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97

25 ~mL, 0.2 MCa(OH)_2 is neutralised by 10 ~mL of 1 MHCl . Then pH of resulting solution is

AIIMS 2011 Solution
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98

The expression for the solubility product of Ag_2 CO_3 will be

JIPMER 2011 Solution
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99

10^ -6 M~ NaOH is diluted 100 times. The pH of the

JIPMER 2011 Solution
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100

A buffer solution is prepared in which the concentration of NH_3 is 0.30 M and the concentration of NH_4^ + is 0.20 M . If the equilibrium constant, K_b for NH_3 equals 1.8 × 10^

NEET 2011 Solution
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101

Which of the following is least likely to behave as Lewis base?

NEET 2011 Solution
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102

In qualitative analysis, the metals of group I can be separated from other ions by precipitating them as chloride salts. A solution initially contains Ag^ + and Pb^ 2+ at a

NEET 2011 Solution
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103

What is the pH of 0.01 M glycine solution? For glycine K_ a_1 =4.5 × 10^ -3 and K_ a_2 =1.7 × 10^ -10 at 298 ~K .

AIIMS 2010 Solution
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104

The standard half-cell reduction potential for Ag^ + Ag is 0.7991 ~V at 25^ ∘ C . Given the experimental value K_ s p =1.56 × 10^ -10 for AgCl , calculate the standard half-cell

AIIMS 2010 Solution
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105

The solubility of saturated solution of Ag_2 CrO_4 is s mol L^ -1 . What is its solubility product?

JIPMER 2010 Solution
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106

Which of the following is a Lewis acid?

JIPMER 2010 Solution
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107

Which one of the following molecular hydrides acts as a Lewis acid ?

NEET 2010 Solution
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108

pH of a 0.01 M solution (K_a=6.6 × 10^ -4 )

AIIMS 2009 Solution
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109

Formula of microcosmic salt is

AIIMS 2009 Solution
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110

Which of the following statement is correct?

JIPMER 2009 Solution
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111

A 0.1 aqueous solution of a weak acid is 2 \% ionised. If the ionic product of water is 1 × 10^ -14 , the [OH^ - ] is

JIPMER 2009 Solution
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112

The correct order of increasing \([H_3 O^ + ]\)in the following aqueous solutions is

AIIMS 2008 Solution
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113

The pH of a 0.001 M solution of HCl is

JIPMER 2008 Solution
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114

The \(pH \) of the solution obtained on neutralisation of \(40 mL 0.1 M NaOH \) with \(40 mL 0.1 M CH _ 3 COOH \) is

AIIMS 2007 Solution
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115

Assertion : Mixture of \(CH_3 COOH\) and \(CH_3 COONH_4\) is an example of acidic buffer. Reason : Acidic buffer contains equimolar mixture of weak acid and its salt with weak

AIIMS 2007 Solution
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116

During titration of acetic acid with aq. \(NaOH\) solution, the neutralisation graph has a vertical line. This line indicates

AIIMS 2007 Solution
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117

At 25^ ∘ C , the dissociation constant of a base, BOH , is 1.0 × 10^ -12 . The concentration of hydroxyl ions in 0.01 M aqueous solution of the base would be

JIPMER 2007 Solution
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118

40 ~mL of 0.1 M ammonia solution is mixed with 20 ~mL of 0.1 MHCl . What is the pH of the mixture? ( p K_b of ammonia solution is 4.74)

AIIMS 2006 Solution
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119

Assertion : Sb_2 ~S_3 is not soluble in yellow ammonium sulphide. Reason : The common ion effect due to S^ 2- ions reduces the solubility of Sb_2 ~S_3 .

AIIMS 2006 Solution
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120

Given pH of a solution A is 3 and it is mixed with another solution B having pH 2 . If both mixed, then resultant pH of the solution will be :

JIPMER 2006 Solution
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