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Identify from the following pair of solutions on mixing exhibits positive deviation from Raoult's law.

Options

  1. AChloroform and acetone
  2. BCarbon disulfide and acetone
  3. CPhenol and aniline
  4. DBenzene and toulene

Correct answer

B. Carbon disulfide and acetone

Step-by-step solution

Chloroform and acetone form intermolecular hydrogen bonds upon mixing, leading to stronger interactions and a negative deviation from Raoult's law. Carbon disulfide and acetone mixture exhibits a positive deviation because the non-polar carbon disulfide molecules disrupt the strong dipole-dipole interactions between acetone molecules, making the solute-solvent interactions weaker than the solute-solute and solvent-solvent interactions. Phenol and aniline form strong intermolecular hydrogen bonds, resulting in a neg

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