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NEET 2024
Exam
NEET
Year
2024
Subject
Chemistry
Chapter
Chemical Kinetics

NEET 2024 · Chemistry · Chemical Kinetics

Rate constants of a reaction at 500 K and 700 K are 0.04 ~s^ -1 and...

Rate constants of a reaction at 500 K and 700∣K700 \mid \mathrm{K} are 0.04 s−10.04 \mathrm{~s}^{-1} and 0.14 s−10.14 \mathrm{~s}^{-1}, respectively; then, activation energy of the reaction is : (Given: log⁡3.5=0.5441,R=8.31 J K−1 mol−1\log 3.5=0.5441, \mathrm{R}=8.31 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}

Options

  1. A182310 J
  2. B18500 J
  3. C18219 J
  4. D18030 J

Correct answer

C. 18219 J

Step-by-step solution

K=Ae−Ea/RT\mathrm{K}=A e^{-E_a / R T} After taking In both side ln⁡K=ln⁡A−EaRT\ln K=\ln A-\frac{E_a}{R T} In⁡K1=ln⁡A−EaRT1\operatorname{In} \mathrm{K}_1=\ln \mathrm{A}-\frac{\mathrm{E}_{\mathrm{a}}}{\mathrm{RT}_1} at temp. T1\mathrm{T}_1...(i) In⁡K2=ln⁡A−EaRT2\operatorname{In} \mathrm{K}_2=\ln \mathrm{A}-\frac{\mathrm{E}_{\mathrm{a}}}{\mathrm{RT}_2} at temp. T2\mathrm{T}_2,,(ii) (ii) - (i) In⁡K2−InK⁡K1=EaR\operatorname{In} K_2-\operatorname{InK} K_1=\frac{E_a}{R}\left[\frac{1}{T_1}-\frac{1}{T_2}\right] \ln \frac{\mathrm{K}_2}{\mathrm{~K}_1}=\frac{\mathrm{E}_{\mathrm{a}}}{\mathrm{R}}[1500−1700]\left[\frac{1}{500}-\frac{1}{700}\right] ln⁡0.140.04=EaR\ln \frac{0.14}{0.04}=\frac{E_a}{R}\left[\frac{700-500}{500 \times 700}\right] \ln \frac{14}{4}=\frac{E_a}{R}[200500×700]\left[\frac{200}{500 \times 700}\right] log⁡3.5=Ea2.303×R\log 3.5=\frac{E_a}{2.303 \times R}\left[\frac{1}{250 \times 7}\right] 0.5441=\frac{E_a}{2.303 \times 8.31}[1250×7]\left[\frac{1}{250 \times 7}\right] Ea=0.5441×8.31×250×7×2.303E_a=0.5441 \times 8.31 \times 250 \times 7 \times 2.303 =0.5441×83.1×25×7×2.303=0.5441 \times 83.1 \times 25 \times 7 \times 2.303 =18222.65=18222.65 ≈18219 J\approx 18219 \mathrm{~J}
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