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NEET 2022
Exam
NEET
Year
2022
Subject
Chemistry
Chapter
Chemical Kinetics

NEET 2022 · Chemistry · Chemical Kinetics

For a first order reaction A → Products, initial concentration of A...

For a first order reaction A→A \to Products, initial concentration of AA is 0.1M0 . 1M, which becomes 0.001M0 . 001M after 55 minutes. Rate constant for the reaction in min⁡−1\min^{- 1} is

Options

  1. A0.92120 . 9212
  2. B0.46060 . 4606
  3. C0.23030 . 2303
  4. D1.38181 . 3818

Correct answer

A. 0.92120 . 9212

Step-by-step solution

The integrated rate equation for a first order reaction is given by

k=2.303tlogaa−xk = \dfrac{2 . 303}{t}log\dfrac{a}{a - x}

Where

k=Rateconstanta=initialconcentrationofthereactantsa−x=concentrationofreactantsleftaftertime,t.k = Rateconstanta = initialconcentrationofthereactantsa - x = concentrationofreactantsleftaftertime, t .

k=2.3035log0.10.001=4.6065=0.9212min⁡−1k = \dfrac{2 . 303}{5}log\dfrac{0 . 1}{0 . 001} = \dfrac{4 . 606}{5} = 0 . 9212\min^{- 1}

Hence, the rate constant of the given reaction is 0.9212min⁡−10 . 9212\min^{- 1}

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