NEET2016ChemistryChemical KineticsActual
The rate of a first-order reaction is 0.04   m o l   l - 1 s - 1 at 10 second and 0.03   m o l   l - 1 s - 1 at 20 seconds after initiation of the reaction. The half-life period of the reaction is:
Options
- A24 . 1   s
- B34 . 1   s
- C44 . 1   s
- D54 . 1   s
Correct answer
A. 24 . 1   s
Step-by-step solution
R a t e T i m e 0.04 10 0.03 20 For first order reaction r ∝ conc. r 1 r 2 = C 1 C 2 = 4 3 ∴ k = 2.303 t 2 - t 1 log C 1 C 2 ⇒ 0.693 t 1 / 2 = 2.303 20 - 10 log 4 3 On solving t 1 / 2 = 24.1 s