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NEET 2008
Exam
NEET
Year
2008
Subject
Chemistry
Chapter
Chemical Kinetics

NEET 2008 · Chemistry · Chemical Kinetics

The rate constants k_1 and k_2 for two different reactions are 10^...

The rate constants k1k_1 and k2k_2 for two different reactions are 1016⋅e−2000/T10^{16} \cdot e^{-2000 / T} and 1015⋅e−1000/T10^{15} \cdot e^{-1000 / T}, respectively. The temperature at which k1=k2k_1=k_2 is

Options

  1. A1000 K1000 \mathrm{~K}
  2. B20002.303K\frac{2000}{2.303} K
  3. C2000 K2000 \mathrm{~K}
  4. D10002.303 K\frac{1000}{2.303} \mathrm{~K}

Correct answer

D. 10002.303 K\frac{1000}{2.303} \mathrm{~K}

Step-by-step solution

Key Idea : The Arrhenius equation is represented as k=Ae−Ea/RTk=A e^{-E_a / R T} In the given equations, first take log and then compare them. k1=1016e−2000/Tk2=1015e−1000/T\begin{aligned} & k_1=10^{16} e^{-2000 / T} \\ & k_2=10^{15} e^{-1000 / T} \end{aligned} On taking log, we get log⁡k1=log⁡1016−20002.303Tlog⁡k2=log⁡1015−10002.303T∵k1=k2\begin{aligned} & \log k_1=\log 10^{16}-\frac{2000}{2.303 T} \\ & \log k_2=\log 10^{15}-\frac{1000}{2.303 T} \\ & \because k_1=k_2 \end{aligned} Hence, from Eqs (i) and (ii) T=10002.303 KT=\frac{1000}{2.303} \mathrm{~K}
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