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NEET 2026
Exam
NEET
Year
2026
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

NEET 2026 · Chemistry · Classification of Elements and Periodicity in Properties

Among the following options, the correct trend in the electron gain...

Among the following options, the correct trend in the electron gain enthalpy is

Options

  1. AI>Br>Cl>F\text{I}>\text{Br}>\text{Cl}>\text{F}
  2. BF>Cl>Br>I\text{F}>\text{Cl}>\text{Br}>\text{I}
  3. CBr>Cl>F>I\text{Br}>\text{Cl}>\text{F}>\text{I}
  4. DCl>F>Br>I\text{Cl}>\text{F}>\text{Br}>\text{I}

Correct answer

D. Cl>F>Br>I\text{Cl}>\text{F}>\text{Br}>\text{I}

Step-by-step solution

The electron gain enthalpy generally becomes less negative as we move down a group due to the increase in atomic size.

However, fluorine has a less negative electron gain enthalpy than chlorine. This is because fluorine has a very small atomic size, leading to strong interelectronic repulsions in the compact 2p2p subshell. As a result, the incoming electron experiences less attraction from the nucleus compared to chlorine.

The values of electron gain enthalpy for halogens are approximately:
Cl=−349 kJ/mol\text{Cl} = -349 \text{ kJ/mol}
F=−328 kJ/mol\text{F} = -328 \text{ kJ/mol}
Br=−325 kJ/mol\text{Br} = -325 \text{ kJ/mol}
I=−295 kJ/mol\text{I} = -295 \text{ kJ/mol}

Considering the magnitude of electron gain enthalpy, the correct trend is Cl>F>Br>I\text{Cl} > \text{F} > \text{Br} > \text{I}.

Answer: Cl>F>Br>I\text{Cl}>\text{F}>\text{Br}>\text{I}
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