NEET2026ChemistryClassification of Elements and Periodicity in PropertiesActual
Among the following options, the correct trend in the electron gain enthalpy is
Options
- AI > Br > Cl > F
- BF > Cl > Br > I
- CBr > Cl > F > I
- DCl > F > Br > I
Correct answer
D. Cl > F > Br > I
Step-by-step solution
The electron gain enthalpy generally becomes less negative as we move down a group due to the increase in atomic size. However, fluorine has a less negative electron gain enthalpy than chlorine. This is because fluorine has a very small atomic size, leading to strong interelectronic repulsions in the compact 2p subshell. As a result, the incoming electron experiences less attraction from the nucleus compared to chlorine. The values of electron gain enthalpy for halogens are approximately: Cl = -349 kJ/mol F = -328