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NEET2026ChemistryClassification of Elements and Periodicity in PropertiesActual

Among the following options, the correct trend in the electron gain enthalpy is

Options

  1. AI > Br > Cl > F
  2. BF > Cl > Br > I
  3. CBr > Cl > F > I
  4. DCl > F > Br > I

Correct answer

D. Cl > F > Br > I

Step-by-step solution

The electron gain enthalpy generally becomes less negative as we move down a group due to the increase in atomic size. However, fluorine has a less negative electron gain enthalpy than chlorine. This is because fluorine has a very small atomic size, leading to strong interelectronic repulsions in the compact 2p subshell. As a result, the incoming electron experiences less attraction from the nucleus compared to chlorine. The values of electron gain enthalpy for halogens are approximately: Cl = -349 kJ/mol F = -328

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