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NEET 2017
Exam
NEET
Year
2017
Subject
Chemistry
Chapter
d and f Block Elements

NEET 2017 · Chemistry · d and f Block Elements

It is because of the inability of ns ^ 2 electrons of the valence...

It is because of the inability of ns2{ns}^{2} electrons of the valence shell to participate in bonding that

Options

  1. ASn2+{Sn}^{2 +} is reducing while Pb4+{Pb}^{4 +} is oxidizing.
  2. BSn2+{Sn}^{2 +} is oxidizing while Pb4+{Pb}^{4 +} is reducing.
  3. CSn2+{Sn}^{2 +} and Pb2+{Pb}^{2 +} are both oxidizing and reducing.
  4. DSn4+{Sn}^{4 +} is reducing while Pb4+{Pb}^{4 +} is oxidizing.

Correct answer

A. Sn2+{Sn}^{2 +} is reducing while Pb4+{Pb}^{4 +} is oxidizing.

Step-by-step solution

The inability of ns2{ns}^{2} electrons of the valence shell to participate in bonding on moving down the group in heavier p−p -block elements is called inert pair effect.

As a result,Pb(II)Pb ( II )is more stable than Pb(IV)Pb ( IV )

Sn(IV)Sn ( IV ) is more stable than Sn(II)Sn ( II )

∴∴ Pb(IV)Pb ( IV ) is easily reduced to Pb(II)Pb ( II ).

∴∴ Pb(IV)Pb ( IV ) is an oxidizing agent.

Sn(II)Sn ( II ) is easily oxidized to Sn(IV)Sn ( IV )

∴∴ Sn(II)Sn ( II )is reducing agent.
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