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NEET 2011
Exam
NEET
Year
2011
Subject
Chemistry
Chapter
d and f Block Elements

NEET 2011 · Chemistry · d and f Block Elements

For the four successive transition elements (Cr, Mn, Fe and Co),...

For the four successive transition elements (Cr, Mn, Fe and Co), the stability of +2 oxidation state will be there in which of the following order? (At. no. Cr=24,Mn=25,Fe=26,Co=27\mathrm{Cr}=24, \mathrm{Mn}=25, \mathrm{Fe}=26, \mathrm{Co}=27 )

Options

  1. AFe >Mn>Co>Cr>\mathrm{Mn}>\mathrm{Co}>\mathrm{Cr}
  2. BCo >Mn>>\mathrm{Mn}> Fe >Cr>\mathrm{Cr}
  3. CCr >> Mn >> Co >> Fe
  4. DMn >> Fe >> Cr >> Co

Correct answer

D. Mn >> Fe >> Cr >> Co

Step-by-step solution

This can be understood on the basis of E∘E^{{}^{\circ}} values for M2+/MM^{2+} / M. E%VCrMnFe Co M2+/M−0.90−1.18−0.44−0.28\begin{array}{lrrcr}E \% V & \mathrm{Cr} & \mathrm{Mn} & \mathrm{Fe} & \text{ Co } \\ M^{2+} / M & -0.90 & -1.18 & -0.44 & -0.28\end{array}E^{{}^{\circ}}value for Mnismorenegativethanexpectedfromgeneraltrendduetoextrastabilityofhalf−filledMn2+\mathrm{Mn} is more negative than expected from general trend due to extra stability of half-filled \mathrm{Mn}^{2+}ion. Thus the correct order should be, Mn>Cr\mathrm{Mn}>\mathrm{Cr}>Fe>COan\mathrm{Fe}>\mathrm{CO}an examination of E∘E^{{}^{\circ}} values for redox couple M3+/M2+M^{3+} / M^{2+} shows that Cr2+isstrongreducing\mathrm{Cr}^{2+} is strong reducing\operatorname{agent}\left(E_{M^{3+}}^{{}^{\circ}} / M^{2+}=0.41  V\mathrm{~V}\right)andliberatesH2and liberates\mathrm{H}_{2} from dilute acids. 2 Cr2+(\mathrm{Cr}^{2+}(a q)+2 \mathrm{H}^{+}(a q) → 2 Cr3+(\mathrm{Cr}^{3+}(a q)+H2↑(q)+\mathrm{H}_2 \uparrow(g) ∴\therefore The correct order is Mn\g\mathrm{Mn} \gt Fe\g\mathrm{Fe} \gt Cr\g\mathrm{Cr} \gt Co.\mathrm{Co}.
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