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NEET 2009
Exam
NEET
Year
2009
Subject
Chemistry
Chapter
d and f Block Elements

NEET 2009 · Chemistry · d and f Block Elements

Which one of the elements with the following outer orbital...

Which one of the elements with the following outer orbital configurations may exhibit the largest number of oxidation states ?

Options

  1. A3d3,4 s23 d^3, 4 \mathrm{~s}^2
  2. B3d5,4 s13 d^5, 4 \mathrm{~s}^1
  3. C3d5,4s23 d^5, 4 s^2
  4. D3d2,4s23 d^2, 4 s^2

Correct answer

C. 3d5,4s23 d^5, 4 s^2

Step-by-step solution

Key Idea Number of oxidation states exhibited by d-block elements is the sum of number of electrons (unpaired) in d-orbitals and number of electrons in s-orbital. (a) 3 d3,4 s2⇒O.S=3+2=53 \mathrm{~d}^3, 4 \mathrm{~s}^2 \Rightarrow \mathrm{O} . \mathrm{S}=3+2=5 (b) 3 d5,4 s1⇒O.S=5+1=63 \mathrm{~d}^5, 4 \mathrm{~s}^1 \Rightarrow \mathrm{O} . \mathrm{S}=5+1=6 (c) 3 d5,4 s2⇒O.S=5+2=73 \mathrm{~d}^5, 4 \mathrm{~s}^2 \Rightarrow \mathrm{O} . \mathrm{S}=5+2=7 (d) 3 d2,4 s2⇒O.S=2+2=43 \mathrm{~d}^2, 4 \mathrm{~s}^2 \Rightarrow \mathrm{O} . \mathrm{S}=2+2=4 Hence, element with 3 d5,4 s23 \mathrm{~d}^5, 4 \mathrm{~s}^2 configuration exhibits largest number of oxidation states.
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