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NEET 2007
Exam
NEET
Year
2007
Subject
Chemistry
Chapter
d and f Block Elements

NEET 2007 · Chemistry · d and f Block Elements

Identify the incorrect statement among the following:

Identify the incorrect statement among the following:Identify the incorrect statement among the following:

Options

  1. ALanthanoid contraction is the accumulation of successive shrinkages
  2. BAs a result of lanthanoid contraction, the properties of 4d4 d series of the transition elements have no similarities with the 5d5 d series of elements
  3. CShielding power of 4f4 f electrons is quite weak
  4. DThee is a decrease in the radii of the atoms or ions as one proceeds from La to Lu\mathrm{Lu}

Correct answer

B. As a result of lanthanoid contraction, the properties of 4d4 d series of the transition elements have no similarities with the 5d5 d series of elements

Step-by-step solution

There is a steady decrease in the radii as the atomic number of the lanthanide elements increases. For every additional proton added in nucleus the corresponding electron goes to 4f4 f subshell. The shape of ff-orbitals is very much diffused and they have poor shielding effect. The effective nuclear charge increases which causes the contraction in the size of electron charge cloud. This contraction in size is quite regular and known as Lanthanoid contraction. Since the change in the ionic radii in the lanthanide series is very small, thus their chemical properties are similar. Identify the incorrect statement among the following:
Related Theory There is no regular trend in ionization potential in the group due to lanthanide contraction. Caution The lanthanide contraction is responsible because Zr\mathrm{Zr} and Hf have about the same radius
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