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NEET 2025
Exam
NEET
Year
2025
Subject
Chemistry
Chapter
Structure of Atom

NEET 2025 · Chemistry · Structure of Atom

The ratio of the wavelengths of the light absorbed by a Hydrogen...

The ratio of the wavelengths of the light absorbed by a Hydrogen atom when it undergoes n=2→n=3\mathrm{n}=2 \rightarrow \mathrm{n}=3 and n=4→n=6\mathrm{n}=4 \rightarrow \mathrm{n}=6 transitions, respectively, is

Options

  1. A136\frac{1}{36}
  2. B116\frac{1}{16}
  3. C19\frac{1}{9}
  4. D14\frac{1}{4}

Correct answer

D. 14\frac{1}{4}

Step-by-step solution

\frac{1}{\lambda}=\mathrm{RZ}^2(1n12−1n22)\left(\frac{1}{\mathrm{n}_1^2}-\frac{1}{\mathrm{n}_2^2}\right) For 2→3⇒1λ1=R×(1)2(122−132)…(1)2 \rightarrow 3 \Rightarrow \frac{1}{\lambda_1}=\mathrm{R} \times(1)^2\left(\frac{1}{2^2}-\frac{1}{3^2}\right) \ldots(1) For 4→6⇒1λ2=R×(1)2(142−162)…(2)4 \rightarrow 6 \Rightarrow \frac{1}{\lambda_2}=\mathrm{R} \times(1)^2\left(\frac{1}{4^2}-\frac{1}{6^2}\right) \ldots(2) Divide (1) & (2) λ2λ1=122−132142−162λ2λ1=41∴λ1λ2=14\begin{aligned} & \frac{\lambda_2}{\lambda_1}=\frac{\frac{1}{2^2}-\frac{1}{3^2}}{\frac{1}{4^2}-\frac{1}{6^2}} \\ & \frac{\lambda_2}{\lambda_1}=\frac{4}{1} \\ & \therefore \frac{\lambda_1}{\lambda_2}=\frac{1}{4} \end{aligned}
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