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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Ionic Equilibrium

NTA Abhyas 2020 · Chemistry · Ionic Equilibrium

Minimum moles of NH _ 3 required to be added to 1L solution so as...

Minimum moles of NH3{NH}_{3} required to be added to 1L1L solution so as to dissolve 0.1mol0 .1 mol of AgCl(Ksp=1.0×10−10)AgCl( {K}_{sp} = 1 .0 \times {10}^{- 10} ) by the reaction is:

{AgCl(s)+2NH3⇌[Ag(NH3)2]++Cl−\begin{cases}\text{AgCl(s)} & + & 2 {NH}_{3} & & ⇌ & {\left[\text{Ag} {\left({NH}_{3}\right)}_{2}\right]}^{+} + & {Cl}^{-} \\ & \end{cases}
Given {K}_{f} \text{of}{\left[{\text{Ag(NH}_{3} {)}_{2}\right]}^{+} {\text{=10}^{8}

Options

  1. A0.5mol0.5 mol
  2. B1.0mol1.0 mol
  3. C1.1mol1.1 mol
  4. D1.2mol1.2 mol

Correct answer

D. 1.2mol1.2 mol

Step-by-step solution

{AgCl(s)+aq⇌Agaq++Claq−;KspAgaq++2NH3aq⇌[Ag(NH3)2aq+];Kf\begin{cases}\text{AgCl} \left(\text{s}\right) & + & \text{aq} & ⇌ & {Ag}_{\text{aq}}^{+} & + & {Cl}_{aq}^{-} & \text{;} & {K}_{sp} \\ {Ag}_{aq}^{+} & + & 2 {NH}_{3 \text{aq}} & ⇌ & \left[\text{Ag} {\left({NH}_{3}\right)}_{2 \text{aq}}^{+}\right] & & & \text{;} & {K}_{f}\end{cases}

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{AgCl(s)+2NH3⇌[Ag(NH3)2aq+]+Claq−K=Ksp×Kf\begin{cases}\text{AgCl} \left(\text{s}\right) & + & 2 {NH}_{3} & ⇌ & \left[\text{Ag} {\left({NH}_{3}\right)}_{2 \text{aq}}^{+}\right] & + & {Cl}_{aq}^{-} & & \text{K} = {K}_{sp} & \times & {K}_{f}\end{cases}

~ & \left(C - 0 .2\right)M0 .1 M0 .1 MEquilibriumconcentration<br/><br/>Equilibrium concentration<br /><br />\text{K} = 1 {0}^{- 1 0} \times 1 {0}^{8} = 1 {0}^{- 2} = \dfrac{\left[\text{Ag} [ {NH}_{3} {)}_{2}^{+}\right] ~\left[{Cl}^{-}\right]}{{\left[{NH}_{3}\right]}^{2}}<br/><br/><br /><br />1 {0}^{- 2} = \dfrac{1 {0}^{- 1} \times 1 {0}^{- 1}}{{\left(\text{M} - 0 \text{.} 2\right)}^{2}}<br/><br/><br /><br />∴ M - 0 .2 = 1<br/><br/><br /><br />∴ M = 1 .2 M
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