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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Polymers

NTA Abhyas 2020 · Chemistry · Polymers

Polyvinyl alcohol is an important polymer. The structure is given...

Polyvinyl alcohol is an important polymer. The structure is given below
Polyvinyl alcohol is an important polymer. The structure is given below It is prepared by polymerization of
It is prepared by polymerization of

Options

  1. ACH2=CH−OHC{H}_{2} = CH - OH
  2. BCH2=CH−OCOCH3C{H}_{2} = CH - OCOC{H}_{3}, followed by hydrolysis
  3. CCH2=CH−CNC{H}_{2} = CH - CN, followed by hydrolysis
  4. DCH2=CH−COOCH3C{H}_{2} = CH - COOC{H}_{3}, followed by hydrolysis

Correct answer

B. CH2=CH−OCOCH3C{H}_{2} = CH - OCOC{H}_{3}, followed by hydrolysis

Step-by-step solution

PVA is prepared by hydrolysis of polyvinyl acetate. Other vinyl ester-derived polymers are sometimes used, with formate, chloroacetate groups instead of acetate. The conversion of the polyesters is usually conducted by base-catalysed transesterification with ethanol:
[CH2CH(OAc)]n+C2H5OH→[CH2CH(OH)]n+C2H5OAc{\left[C{H}_{2}CH\left(OAc\right)\right]}_{n} + {C}_{2}{H}_{5}OH \to {\left[C{H}_{2}CH\left(OH\right)\right]}_{n} + {C}_{2}{H}_{5}OAc
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