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NTA Abhyas JEE Main2020ChemistryPolymersPractice

Under hydrolytic conditions, the compounds used for preparation of linear polymer and for chain termination, respectively, are

Options

  1. AC H 3 SiC l 3 and S i C H 3 4
  2. BC H 3 2 S i C l 2 and C H 3 3 S i C l
  3. CC H 3 2 S i C l 2 and C H 3 SiC l 3
  4. DSiC l 4 and C H 3 3 S i C l

Correct answer

B. C H 3 2 S i C l 2 and C H 3 3 S i C l

Step-by-step solution

Under hydrolytic conditions, the compound used for the preparation of linear polymer and for chain termination are ( C H 3 ) 2 SiC l 2 and ( C H 3 ) 3 SiCl respectively. The hydrolysis of dimethyldichlorosilane gives dimethyl silane diol which on condensation polymerization forms a linear polymer. The hydrolysis of trimethylchlorosilane gives trimethyl silanol which can not undergo polymerization as it contains only one -OH group so it is used for chain termination.

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