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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
s Block Elements

NTA Abhyas 2020 · Chemistry · s Block Elements

In the following reactions, products (X) and (Y) respectively are...

In the following reactions, products (X)\text{(X)} and (Y)\text{(Y)} respectively are

NaOH(hot and conc.)+Cl2→(X)+\mathop{\text{NaOH}}_{\left(\text{hot and conc}\text{.}\right)} \text{+}{\text{Cl}}_{2} \to \text{(X)}\text{+} side products

Ca(OH)2(dry)+Cl2→(Y)+\mathop{{\text{Ca(OH)}}_{2}}_{\left(\text{dry}\right)} + {\text{Cl}}_{2} \to \text{(Y)} + side products

Options

  1. ANaOCl and Ca(ClO3)2\text{Ca} ( \text{Cl}{\text{O}}_{3}{)}_{2}
  2. BNaClO3\text{NaCl}{\text{O}}_{3} and Ca(OCl)2\text{Ca} ( \text{OCl}{)}_{2}
  3. CNaOCl and Ca(OCl)2\text{Ca} ( \text{OCl}{)}_{2}
  4. DNaClO3\text{NaCl}{\text{O}}_{3} and Ca(ClO3)2\text{Ca} ( \text{Cl}{\text{O}}_{3}{)}_{2}

Correct answer

B. NaClO3\text{NaCl}{\text{O}}_{3} and Ca(OCl)2\text{Ca} ( \text{OCl}{)}_{2}

Step-by-step solution

Here the products formed (X) and (Y) are NaClO3\text{NaCl}{\text{O}}_{3} and Ca(OCl)2\text{Ca} ( \text{OCl}{)}_{2} respectively
6NaOH+3Cl2→5NaCl+NaClO3+3H2O\text{6}\text{NaOH} + \text{3}{\text{Cl}}_{\text{2}} \to \text{5}\text{NaCl} + {\text{NaClO}}_{\text{3}} + \text{3}{\text{H}}_{\text{2}} \text{O}
2Ca(OH)2+Cl2→Ca(OCl)2+CaCl2+H2O\text{2}{\text{Ca(OH)}}_{\text{2}} + {\text{Cl}}_{\text{2}} \to {\text{Ca(OCl)}}_{\text{2}} + {\text{CaCl}}_{\text{2}} + {\text{H}}_{\text{2}} \text{O}
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