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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
s Block Elements

NTA Abhyas 2020 · Chemistry · s Block Elements

A solid compound X on heating gives C O _ 2 gas and a residue. The...

A solid compound X on heating gives CO2C{O}_{2} gas and a residue. The residue mixed with water forms Y. On passing an excess of CO2C{O}_{2} through Y in water, a clear solution Z is obtained. On boiling Z, compound X is reformed. The compound X is

Options

  1. ACa{\left(HC{O}_{3}\right)}_{2}
  2. BCaCO3CaC{O}_{3}
  3. CNa2CO3N{a}_{2}C{O}_{3}
  4. DK2CO3{K}_{2}C{O}_{3}

Correct answer

B. CaCO3CaC{O}_{3}

Step-by-step solution

The given compound X must be CaCO3CaC{O}_{3}. It can be explained by following reaction

CaCO3→ΔCaO+CO2↑CaC{O}_{3}\overset{\Delta}{→}CaO + C{O}_{2} ↑

CaO+H2O→Ca( OH )2CaO + {H}_{2}O \to \mathop{Ca{\left(\text{ OH }\right)}_{2}}_{\left(Y\right)}<br/><br/><br/><br/>Ca{\left(OH\right)}_{2} + 2C{O}_{2} + {H}_{2}O \to \mathop{Ca{\left(HC{O}_{3}\right)}_{2}}_{\left(Z\right)}<br/><br/><br/><br/>Ca{\left(HC{O}_{3}\right)}_{2}\overset{\Delta}{→}\mathop{CaC{O}_{3}}_{\left(X\right)} + C{O}_{2} ↑ + {H}_{2}O
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