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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
s Block Elements

NTA Abhyas 2020 · Chemistry · s Block Elements

The solubility of alkali metal salts in water is due to the fact...

The solubility of alkali metal salts in water is due to the fact that the cations get hydrated by water molecules.
What is the relative degree of hydration?

Options

  1. ACs( aq )C{s}_{\left(\text{ aq }\right)}^{+} > R{b}_{\left(aq\right)}^{+} > {K}_{\left(aq\right)}^{+} > N{a}_{\left(aq\right)}^{+} > L{i}_{\left(aq\right)}^{+}
  2. BLi( aq )L{i}_{\left(\text{ aq }\right)}^{+} > N{a}_{\left(aq\right)}^{+} > {K}_{\left(aq\right)}^{+} > R{b}_{\left(aq\right)}^{+} > C{s}_{\left(aq\right)}^{+}
  3. CNa( aq )N{a}_{\left(\text{ aq }\right)}^{+} > {K}_{\left(aq\right)}^{+} > R{b}_{\left(aq\right)}^{+} > C{s}_{\left(aq\right)}^{+} > L{i}_{\left(aq\right)}^{+}
  4. DCs( aq )C{s}_{\left(\text{ aq }\right)}^{+} > N{a}_{\left(aq\right)}^{+} > L{i}_{\left(aq\right)}^{+} > {K}_{\left(aq\right)}^{+} > R{b}_{\left(aq\right)}^{+}

Correct answer

B. Li( aq )L{i}_{\left(\text{ aq }\right)}^{+} > N{a}_{\left(aq\right)}^{+} > {K}_{\left(aq\right)}^{+} > R{b}_{\left(aq\right)}^{+} > C{s}_{\left(aq\right)}^{+}

Step-by-step solution

As hydration energy ∝∝ charge on cation ∝1size of cation∝ \dfrac{1}{\text{size of cation}}
As on moving down size of ion increases so degree of hydration decreases hence the correct order is
Li( aq )L{i}_{\left(\text{ aq }\right)}^{+} > N{a}_{\left(aq\right)}^{+} > {K}_{\left(aq\right)}^{+} > R{b}_{\left(aq\right)}^{+} > C{s}_{\left(aq\right)}^{+}
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