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Concentrated aqueous sodium hydroxide can separate a mixture of

Options

  1. AA l 3 + and S n 2 +
  2. BA l 3 + and F e 3 +
  3. CA l 3 + and Z n 2 +
  4. DZ n 2 + and P b 2 +

Correct answer

B. A l 3 + and F e 3 +

Step-by-step solution

Concentrated aqueous sodium hydroxide can separate a mixture of A l 3 + and F e 3 + A l 3 + forms white gelatinous precipitate of A l O H 3 , which is soluble in excess of NaOH. A l O H 3 + N a O H → N a A l O 2 + 2 H 2 O F e 3 + forms reddish brown precipitate of F e O H 3 , which is insoluble in excess of NaOH.

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