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The following data were obtained from the first order decomposition of 2 A g → B g + C ( S ) at a constant volume and at a particular temperature S No. Time Total pressure in Pascal 1 At the end of 10 min 300 2 After completion 200 The rate constant in min -1 is

Options

  1. A0.0693
  2. B69.3
  3. C6.93
  4. D6.93 × 10 - 4

Correct answer

A. 0.0693

Step-by-step solution

2 A → B + C t = 0 2 P 0 - After 10 min 2 P - 2x x - After completion 0 P - Given, P = 200 after the completion 2 P - x = 300 (at the end of 10 min) x = 100 k = 2.303 10 l o g 200 100 = 0.0693 m i n - 1

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