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NEET
Exam
NEET
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Physics
Chapter
Kinetic Theory of Gases

NEET · Physics · Kinetic Theory of Gases

Two different ideal gases, X and Y, are kept in separate identical...

Two different ideal gases, X and Y, are kept in separate identical flasks at the exact same temperature and pressure. If the mean free path of the molecules of gas X is 99 times that of gas Y, what is the ratio of the molecular diameters of gas X to gas Y?

Options

  1. A3:13:1
  2. B1:31:3
  3. C1:91:9
  4. D9:19:1

Correct answer

B. 1:31:3

Step-by-step solution

For an ideal gas, the number density nn is given by n=PkBTn = \dfrac{P}{k_B T}.

Since both gases are at the same pressure and temperature, their number densities are equal (nX=nYn_X = n_Y).

The mean free path is given by λ=12πd2n\lambda = \dfrac{1}{\sqrt{2}\pi d^2 n}.

Since nn is constant across both flasks, λ∝1d2\lambda \propto \dfrac{1}{d^2}.

Therefore, λXλY=(dYdX)2\dfrac{\lambda_X}{\lambda_Y} = \left(\dfrac{d_Y}{d_X}\right)^2

Given λX=9λY\lambda_X = 9\lambda_Y, we have:

9=(dYdX)29 = \left(\dfrac{d_Y}{d_X}\right)^2

dYdX=3\dfrac{d_Y}{d_X} = 3

dXdY=13\dfrac{d_X}{d_Y} = \dfrac{1}{3}

The ratio of their molecular diameters is 1:31:3.

Answer: 1:31:3
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