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NEET
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Physics
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Atomic Physics

NEET · Physics · Atomic Physics

In a hydrogen atom, the ratio of the kinetic energies of an...

In a hydrogen atom, the ratio of the kinetic energies of an electron in two states A and B is 9:19:1. If state A is the first excited state, then state B is the

Options

  1. A2nd2^{\text{nd}} excited state
  2. B5th5^{\text{th}} excited state
  3. C17th17^{\text{th}} excited state
  4. DGround state

Correct answer

B. 5th5^{\text{th}} excited state

Step-by-step solution

The kinetic energy of an electron in the nthn^{\text{th}} orbit of a hydrogen atom is inversely proportional to the square of the principal quantum number nn, i.e., K∝1n2K \propto \dfrac{1}{n^2}.

Given the ratio of kinetic energies in states A and B is KA:KB=9:1K_A : K_B = 9:1.

Therefore, KAKB=nB2nA2=9\dfrac{K_A}{K_B} = \dfrac{n_B^2}{n_A^2} = 9

State A is the first excited state, which corresponds to nA=2n_A = 2.

Substituting nA=2n_A = 2 into the equation:
nB222=9\dfrac{n_B^2}{2^2} = 9
nB2=9×4=36n_B^2 = 9 \times 4 = 36
nB=6n_B = 6

The principal quantum number n=6n=6 corresponds to the 5th5^{\text{th}} excited state.

Assuming the first excited state is n=1n=1 leads to the incorrect answer of the 2nd2^{\text{nd}} excited state. Forgetting to square the quantum numbers leads to the 17th17^{\text{th}} excited state.

Answer: 5th5^{\text{th}} excited state
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