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NEET
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Physics
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Atomic Physics

NEET · Physics · Atomic Physics

An electron in a singly ionized helium atom ( He^+ ) is in an...

An electron in a singly ionized helium atom (He+He^+) is in an excited state where its orbital angular momentum is 2hπ\dfrac{2h}{\pi}. If it makes a transition to a state with orbital angular momentum hπ\dfrac{h}{\pi}, the wavelength of the emitted photon is (where RR is the Rydberg constant):

Options

  1. A163R\dfrac{16}{3R}
  2. B43R\dfrac{4}{3R}
  3. C3R4\dfrac{3R}{4}
  4. D13R\dfrac{1}{3R}

Correct answer

B. 43R\dfrac{4}{3R}

Step-by-step solution

Given, initial angular momentum Li=2hπ=nih2π⇒ni=4L_i = \dfrac{2h}{\pi} = n_i \dfrac{h}{2\pi} \Rightarrow n_i = 4

Final angular momentum Lf=hπ=nfh2π⇒nf=2L_f = \dfrac{h}{\pi} = n_f \dfrac{h}{2\pi} \Rightarrow n_f = 2

For a singly ionized helium atom (He+He^+), the atomic number Z=2Z = 2.

The wavelength λ\lambda of the emitted photon is given by the Rydberg formula:

1λ=RZ2(1nf2−1ni2)\dfrac{1}{\lambda} = R Z^2 \left( \dfrac{1}{n_f^2} - \dfrac{1}{n_i^2} \right)

⇒1λ=R(2)2(122−142)\Rightarrow \dfrac{1}{\lambda} = R (2)^2 \left( \dfrac{1}{2^2} - \dfrac{1}{4^2} \right)

⇒1λ=4R(14−116)\Rightarrow \dfrac{1}{\lambda} = 4R \left( \dfrac{1}{4} - \dfrac{1}{16} \right)

⇒1λ=4R(316)=3R4\Rightarrow \dfrac{1}{\lambda} = 4R \left( \dfrac{3}{16} \right) = \dfrac{3R}{4}

⇒λ=43R\Rightarrow \lambda = \dfrac{4}{3R}

Using Z=1Z=1 incorrectly leads to 163R\dfrac{16}{3R}, and misinterpreting the angular momentum values as n=2n=2 and n=1n=1 leads to 13R\dfrac{1}{3R}.

Answer: 43R\dfrac{4}{3R}
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