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NEETChemistryClassification of Elements and Periodicity in Properties

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Element X ( IE ₁ = 495 kJ mol ⁻¹ , IE ₂ = 4562 kJ mol ⁻¹ ) is more metallic and forms a more basic oxide than Element Y ( IE ₁ = 737 kJ mol ⁻¹ , IE ₂ = 1450 kJ mol ⁻¹ , IE ₃ = 7732 kJ mol ⁻¹ ) which belongs to the same period. Reason (R): The large jump between the first and second ionization entha

Options

  1. ABoth Assertion and Reason are correct and Reason is the correct explanation for Assertion.
  2. BBoth Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
  3. CAssertion is correct but Reason is incorrect.
  4. DAssertion is incorrect but Reason is correct.

Correct answer

C. Assertion is correct but Reason is incorrect.

Step-by-step solution

Assertion (A) is correct: For element X, the massive jump between IE ₁ and IE ₂ ( 495 to 4562 kJ mol ⁻¹ ) indicates it has 1 valence electron, so it belongs to Group 1 (alkali metals). For element Y, the massive jump is between IE ₂ and IE ₃ ( 1450 to 7732 kJ mol ⁻¹ ), indicating it has 2 valence electrons, so it belongs to Group 2 (alkaline earth metals). In a given period, Group 1 elements have larger atomic radii and lower effective nuclear charge than Group 2 elements, making them more metallic and their oxides

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