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NEET
Exam
NEET
Subject
Chemistry
Chapter
Redox Reactions

NEET · Chemistry · Redox Reactions

The exhibition of various oxidation states by an element is also...

The exhibition of various oxidation states by an element is also related to the outer orbital electronic configuration of its atom. Atom (s) having which of the following outermost electronic configurations will exhibit more than one oxidation state in its compounds. (a) (3 \mathrm{~s}^{\prime}) (b) (3 d^{\prime} 4 s^2) (c) 3d24s23 d^2 4 s^2 (d) 3s23p33 s^2 3 p^3

Options

  1. AOnly A is correct
  2. BOnly A,B,CA, B, C is correct
  3. COnly C,DC, D is correct
  4. DOnly B,C,D is correct

Correct answer

D. Only B,C,D is correct

Step-by-step solution

Elements which have only s-electrons in the valence shell do not show more than one oxidation state. Thus, element with 3s13 s^1 as outer electronic configuration shows only one oxidation state of +1. Transition element such as elements (b), (c) having incompletely filled dd-orbitals in the penultimate shell show variable oxidation states. Thus, element with outer electronic configuration as 3d14s23 d^1 4 s^2 shows variable oxidation states of +2 and +3 and the element with outer electronic configuration as 3d24s23 d^2 4 s^2 shows variable oxidation states of +2,+3+2,+3 and +4. p-Block elements also show variable oxidation states due to a number of reason such as involvement of dd-orbitals and inert pair effect e.g., element (d) with 3s23p33 s^2 3 p^3 as (i.e., P) as the outer electronic configuration shows variable oxidation states of +3 and +5 due to involvement of dd-orbitals.
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