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Vapour pressures of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot p total , p chloroform , and p acetone as a function of x acetone . The experimental data observed for different compositions of mixture is: Indicate whether it has positive deviation or negative deviation from the ideal solution.

Options

  1. AThe solution shows negative deviation from Raoult's law.
  2. BThe solution shows positive deviation from Raoult's law.
  3. CThe solution shows both positive and negative deviation from Raoult's law.
  4. DThe solution strictly follows Raoult's law, showing no deviation

Correct answer

A. The solution shows negative deviation from Raoult's law.

Step-by-step solution

Correct Option is : (A) The solution shows negative deviation from Raoult's law.

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