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AIIMS 2010
Exam
AIIMS
Year
2010
Subject
Chemistry
Chapter
Thermodynamics (C)

AIIMS 2010 · Chemistry · Thermodynamics (C)

Assertion : Bond energy and bond dissociation energy have identical...

Assertion : Bond energy and bond dissociation energy have identical value for diatomic molecules. Reason : Greater the bond dissociation energy, less reactive is the bond.

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of assertion
  2. BIf both assertion and reason are true but reason is not the correct explanation of assertion
  3. CIf assertion is true but reason is false
  4. DIf both assertion and reason are false.

Correct answer

B. If both assertion and reason are true but reason is not the correct explanation of assertion

Step-by-step solution

Bond dissociation energy is the energy required to break a particular bond in one mole of a gaseous molecule. Bond energy is the average values of dissociation energies of the same type of bond present in the molecule. Bond energy of C−H\mathrm{C}-\mathrm{H} bond in methane is 99.2kcal/mol99.2 \mathrm{kcal} / \mathrm{mol}. Thus for polyatomic molecules, average bond energy is taken as the dissociation bond energy.
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