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AIIMS 2003
Exam
AIIMS
Year
2003
Subject
Chemistry
Chapter
Thermodynamics (C)

AIIMS 2003 · Chemistry · Thermodynamics (C)

Assertion : The increase in internal energy (Δ E) for the...

Assertion : The increase in internal energy (ΔE)(\Delta E) for the vapourization of one mole of water at 1 atm1 \mathrm{~atm} and 373 K373 \mathrm{~K} is zero. Reason : For all isothermal processes, ΔE=0\Delta E=0.

Options

  1. AIf both assertion and reason are true and the reason is the correct explanation of the assertion
  2. BIf both assertion and reason are true and the reason is not the correct explanation of the assertion
  3. CIf assertion is true but reason is false
  4. DIf both assertion and reason are false.

Correct answer

A. If both assertion and reason are true and the reason is the correct explanation of the assertion

Step-by-step solution

At 373 K373 \mathrm{~K} or 100∘C100^{\circ} \mathrm{C}, the water starts boiling and at this temperature the vaporization of water is an isothermal process. The internal energy change (ΔE)(\Delta E), depend only on temperature, it follows that at constant temperature, the internal energy of the gas remains constant, i.e. ΔE\Delta E is zero.
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